All-inorganic CsPbI3 halide perovskite quantum dots have high quantum efficiency, unique band gap and narrow band emission characteristics, and are widely considered to be competitive candidates for pure red light-emitting diodes (LEDs). However, the stability of CsPbI3 perovskite quantum dots and the large-area film-forming process are the main obstacles to their practical application in the LED field. In this work, we successfully improved the luminescence intensity and stability of CsPbI3 perovskite quantum dots by using Mg2+ / Yb3+ co-doping strategy. The luminescence intensity of CsPbI3 quantum dots after ion doping regulation is increased by 1.92 times. In addition, the CsPbI3 perovskite nanocrystals after ion doping regulation still maintain high optical stability after being placed at 120 °C for 70 minutes and 10 days in the external environment, respectively. Based on these perovskite nanocrystals, we also fabricate large-scale patterned LEDs (25.4 mm×25.4 mm). At a bias voltage of 6 V, the fabricated LEDs exhibit a luminance of 749 cd m-2. At a current density of 6.4 mA cm-2, the fabricated LEDs achieve an external quantum efficiency of 10.9%. This result is expected to fuel the rapid growth of large-area pure red LEDs.
Related publications:
1. Ionic doping of CsPbI3 perovskite nanocrystals improves luminescence and stability in patterned large-area light-emitting diodes
Lv, H.; Tang, X.; Chen, M., ACS Appl. Nano Mater. 2023, 6, 20, 18918-18925.
E-mail: menglu@bit.edu.cn
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